Maybe because I've been really into JJBA lately, but I'd LOVE to see an otome li like Gyro Zeppeli (JJBA Part 7), adding Dante from Devil May Cry too because I saw another reply mentioning him. I think they both have one of my favorite character archetypes, which is the goofy/weird/eccentric(?), unserious guy who is also very competent/skilled at their job and/or at fighting, and can turn really serious when doing it. I think Hoshina from Kaiju No. 8 also falls into this category.
Maybe I just haven't played enough otome games yet, but I haven't really seen this type of li. The closest I could think of is Seiya from 9 RIP, who is also my 2nd favorite li in that game.